Level of study
BAC +4
ECTS
2 credits
Component
Faculty of Science
Description
A general approach to liquid-liquid extraction will be developed through thermodynamic and kinetic notions in order to understand the mechanisms responsible for extraction as well as the processes taking place at the liquid-liquid interface. Fundamental aspects of other types of extraction (liquid-solid, supercritical fluid, distillation) will also be discussed.
Hourly volumes* :
CM : 12h
TD : 8h
Objectives
The objective of this course is to provide an inventory of the fundamental data on the kinetics and thermodynamics of liquid-liquid extraction. It will also present the main concepts and processes inherent to extraction (liquid-liquid, liquid-solid or critical fluid) and distillation.
Necessary pre-requisites
Solution chemistry
Complements in solution chemistry
Solution chemistry applied to actinides
Knowledge control
Continuous control
Syllabus
- Kinetics and thermodynamics in homogeneous phase.
- Thermodynamics in liquid-liquid extraction
- Determination and meaning of the different quantities
- Presentation of extraction mechanisms and associated constants
- Analysis of enthalpic and entropic contributions.
- Kinetics in liquid-liquid extraction
- Diffusional term and chemical kinetics (laws describing the phenomena)
- The liquid-liquid interface (description, physicochemical properties...)
- Definition and identification of the limiting regime (examples)
- Experimental techniques
- Systems minimizing the diffusional contribution (Lewis cells, single drop)
- Systems controlling the diffusional term (rotating cell)
- Fundamental aspects and applications in the following areas:
- Liquid-Liquid Extraction
- Liquid-Solid Extraction
- Extraction by supercritical fluids
- Distillation
The teaching will include tutorials related to industrial problems but will also include bibliographic tutorials.
Additional information
Administrative contact(s): Secretariat Master Chemistry