Coordination Chemistry of f-Block Elements

A general overview of the coordination chemistry of the f-elements will be presented through the concepts of atomistics, oxidation state, and coordination polyhedra, with the aim of highlighting the specific characteristics of the f-elements. Direct comparisons will be made with the coordination chemistry of transition metals, and applications related to nuclear chemistry will be discussed.

Hourly volumes*:

            CM: 12:00 p.m.

            TD: 8:00 a.m.

The objective of this course is to introduce students to the coordination chemistry of the lanthanide and actinide elements, as well as to the unique properties of f orbitals, by drawing comparisons with the d elements.

Concepts in coordination chemistry and atomistics.

Solution Chemistry Applied to Actinides

Comprehensive Continuous Monitoring

A General Approach to the Specificity of the Elements f:

- Electronic and atomistic configuration; a qualitative approach to relativistic effects

- Ionic radii, properties of the elements

• Orbitals f (symmetry and localization):

- Comparison with the orbitals of d

- The case of the uranyl ion

- Spectroscopic Approach (Basics)

• Oxidation states:

- Differences between lanthanides and actinides

- Coordination polyhedra, comparison with the elements of

• Application to Nuclear Chemistry. The HSAB Approach

The course will consist of lectures, tutorials, and assignments based on published materials.

Administrative contact(s): Chemistry Master's Program Office

Master's in Chemistry @ umontpellier.fr