M1 - Materials for Low-Carbon Energy (MatEBaC)

The professional project bridges the gap between traditional practical work and internships in laboratories or companies. It takes the form of a supervised project consisting of placing students in a professional situation through collaborative (group) work based on carrying out a project in response to a problem set by a company, local authority, association, or academic. It is part of the core curriculum of the Master's in Chemistry and is carried out under the supervision of a member of the teaching team (academic or industrial). Conducted throughout the semester, this project aims to connect and consolidate the knowledge and skills acquired during the Bachelor's and early Master's programs through this professional situation. These scenarios will be directly related to the Master's program chosen by the students. In addition to chemistry-specific skills, other interpersonal, organizational, and communication skills intrinsically linked to project management will also be acquired, equipping students for their future professional lives.

Addressing a research issue: example of a summary of new phosphorescent materials.

Hourly volumes:

CM: 5 hours

Tutorial: 5 hours

Practical work: 40 hours

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Polymers are all around us: we eat them, we wear them, and we use them to construct extremely complex buildings. From mature technologies to the most innovative materials, polymers are a crucial building block for constructing the world of tomorrow. In this course, we will cover several aspects such as the controlled synthesis of polymers and cross-linked materials, surface modification using polymers, some characterization tools suitable for polymers, and finally a last section developing the latest advances involving polymers.

Hourly volumes:

            CM: 1:00 p.m.

            Tutorial: 7 hours

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The program of this EU focuses on describing the principles and applications of the main methods for the structural characterization of solids, thin films, surfaces, and interfaces, as well as several examples of applications in materials chemistry. It includes the following techniques.

• Introduction to solid-state NMR (NMR signal, interactions in solid-state NMR, magic angle spinning, NMR sequences, cross polarization, instrumentation, etc.)
• Electron microscopy: principles and applications of scanning and transmission electron microscopy and related techniques (EDS microanalysis).
• Spectroscopic methods: Raman spectroscopy, photoelectron spectroscopy, X-ray spectroscopy (XAS, XRF, etc.), Mössbauer spectrometry.

Hourly volumes:

            CM: 10 a.m.

            Tutorial: 10 a.m.

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The HAC720C module covers "advanced inorganic materials" in five main sections. The^first section is devoted to general information on inorganic materials and discusses structure-property relationships, with particular attention paid to chemical bonding, real crystals, and polycrystalline solids. The different classes of inorganic materials are described. The^second part focuses on ceramic materials (definitions and properties) and their synthesis (raw materials including clays, shaping, drying and debinding, sintering); a distinction is made between traditional ceramics and technical ceramics (synthesis methods for oxide and non-oxide ceramics). The^third part covers glass (classification and synthesis methods) and glass-ceramics (devitrification and soft chemistry); their properties and applications are also discussed. The^fourth part is dedicated to metals: properties of metals and metal alloys; metal nanoparticles; and catalytic materials. Part⁵ is devoted to inorganic materials developed for energy; ceramics (oxides and non-oxides; nanostructured) and metal hydrides are described (properties and synthesis) through several examples and in the context of their applications (accumulators, hydrogen storage, and carbon dioxide capture).

Hourly volumes:

CM: 1:00 p.m.

Tutorial: 7 hours

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- Review of thermodynamics of single-component systems.

- Basic concepts of thermodynamics in multicomponent systems. Chemical potential, Gibbs-Duhem relation, variance.

- Concepts related to thermal analysis techniques used to construct binary/ternary diagrams: ATG, ATD, and DSC

- Construction and interpretation of binary phase diagrams based on thermodynamic quantities. Gibbs free enthalpy, pressure, and temperature diagrams as a function of the composition of the binary mixture. Liquid-liquid, liquid-vapor, and solid-liquid mixtures.

- Phase transformations: first- and second-order transitions, critical points. Examples.

- The supercritical state: definition, thermodynamic properties, most widespread industrial applications.

- Construction and interpretation of ternary phase diagrams: variance, definitions of ternary eutectic, first and second order peritectic, isothermal section, study of alloy cooling.

Hourly volumes:

CM: 13

TD: 7

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This teaching unit covers the various basic elements needed to understand natural and artificial radioactivity phenomena. It aims to establish all the concepts related to decay phenomena, natural radioactive families and their associated environmental consequences, dating methods, methods of producing radionuclides and their use in various fields, as well as anthropogenic contributions. Various examples from industry, nuclear energy, radiochemistry, geochemistry, and nuclear medicine will be used to illustrate the basic concepts covered.

Hourly volumes:

CM: 12 p.m.

Tutorial: 8 hours

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This teaching unit covers the various aspects of the current fuel cycle and future nuclear cycles. It will cover concepts relating to the front end of the cycle (mineral resources, uranium extraction and purification, isotopic enrichment), the passage of fuels through nuclear reactors, and the back end of the cycle (reprocessing of spent fuel, recycling of recoverable materials and fuel remanufacturing, management of final nuclear waste). This will be followed by several aspects relating to future nuclear fuel cycles, in particular the use of unconventional resources, advanced separation concepts, and the development of fourth-generation reactors.

Hourly volumes:

            CM: 3 p.m.

            Tutorial: 5 hours

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